Carbon Cycle has developed a novel method to purify gypsum that could transform the supply of gypsum to the Indian cement sector...
Global Cement (GC): Could you introduce your background and how Carbon Cycle was set up?
David Sevier (DS): I am an industrial chemist by training and have mainly worked in the water treatment sector. The company that I worked for established Carbon Cycle to look at capturing CO2 emissions. This involved reacting gypsum with ammonia and CO2 to make calcium carbonate. We were working on a process that needed very pure calcium carbonate, which, in turn, required a purification process for gypsum.
We found that there was no established chemical process to purify gypsum and so set about developing a novel approach. The process was developed intensely for around two and a half years. We received a lot of interest from a number of sectors, including cement, and gypsum purification quickly became Carbon Cycle’s main focus.
GC: When was the switch in emphasis from CO2 capture to the gypsum purification process?
DS: The process was first used to purify chalk, initially with limited success. Then we tried a new approach in late 2016. The engineer running the trial almost leapt out of the laboratory, saying, ‘You’ve got to come and see this!’ It was a proper ‘Eureka moment.’ It was the whitest chalk we had ever seen, exceeding anything we could find on the market. His innovation was to apply the new approach to purifying gypsum. It worked just as well.
GC: Please could you outline the new process?
DS: Carbon Cycle’s patented process involves placing impure gypsum into a solution of ammonium sulphate at 90 - 100°C, very hot but not boiling. After five minutes the gypsum forms a complex with the ammonium sulphate. The complex sinks in the solution while releasing the impurities previously trapped within the gypsum mass. The complex is filtered from the hot solution. The complex is then placed in water at a lower temperature, where it reverts to ammonium sulphate solution and pure gypsum.
GC: It sounds devilishly simple…
DS: In some ways it is, but the devil is in the detail. It took time to get the parameters spot on. Different industries have different requirements as to how their gypsum ‘should be.’ We anticipate a tuneable process that can meet most requirements. We can already alter the moisture content and adjust the back end of the process to affect the phase, crystal size and whether the product is hemi-hydrate or di-hydrate.
GC: What’s the next step?
DS: We are in discussion with a number of parties regarding the construction of a pilot plant. We will start a 500kg batch trial in the coming weeks.
GC: Which sectors have the most to gain from a commercial version of this process?
DS: On the producer side, the industry with the most by-product of ‘waste’ gypsum is undoubtedly phosphoric acid production. Indeed, several producers in this sector are having a hard time commercially at the moment. Gypsum purification, and the sale of impurities from the input gypsum, could provide much needed new revenue streams for them. You can fill Wembley Stadium to the brim every 36 hours with gypsum waste from the phosphoric acid sector, amounting to 300Mt/yr! This currently sits in waste piles containing many billions of tonnes of gypsum. There are huge liability costs associated with that material sitting around. We could easily supply existing gypsum demand if that phosphogypsum was to be purified using the Carbon Cycle process.
On the user side, the most opportunity is probably in the Indian cement sector. Without natural gypsum at home and scrubbers on coal-fired power plants not yet common, cement producers must import gypsum from far afield, places like Morocco, Thailand or Oman. This can cost them as much as US$30/t landed at port. By the time it reaches the cement plant it could cost US$50/t, which is a lot. Just think: There are big piles of phosphogypsum in India, many of which are right next to railway lines. Some are even next to cement plants. If purified, it would be far cheaper to use this resource instead of expensive imports. There would be savings with regard to ongoing liabilities, as well as the cost of adding lime to neutralise the phosphoric acid, which costs around US$7 - 8/t.
The same argument applies to the Indonesian cement sector, as well as many places in Africa. In Europe there are incinerators that produce a form of FGD contaminated with toxic impurities. The process will remove these. That could be excellent news for European gypsum users that are becoming concerned over where future supplies might come from.
GC: You mentioned ‘impurities’ there and alluded to their value earlier. What are they and how do they fit into the process?
DS: Almost every gypsum feedstock we have trialled has been ‘hiding’ something interesting. The biggest opportunity on this side will certainly be the rare earth metals, the most interesting of which are neodymium and praeseodymium. Both of these are magnetic and are very important for electric motors in cars and for generators in wind turbines. China has around 97% of the concentrated resources for each of these, which have been largely kept for use by Chinese firms. Other sources of these metals outside of China would be a game-changer for green-tech companies throughout the world.
In another example, one source was found to contain rubidium at >100ppm. Total global production of rubidium is just ~4t/yr. It’s clear that there are commercial benefits of optimising the process to purify and sell this material. The process also separates out radioactive elements.
GC: What needs to happen before this process can be commercialised?
DS: The next and final step before commercialisation is our integrated pilot plant. This will take us 9-12 months to demonstrate in full. Afterwards, we will select partners to build the first commercial plant, which will be located at a phosphoric acid plant. Going forward, we will licence the technology to individual sites, most of which are anticipated to be phosphoric acid producers.
The ‘package’ will include a range of stakeholders. A phosphoric acid plant designer will work out how to link the new equipment to the existing plant and to cost up a design. There will be also be introductions to rare earth off-takers and gypsum off-takers like cement producers. The phosphoric acid plant would pay a licence fee. Given the tricky operating environment in this sector at the moment, this would be a win-win-win situation.
GC: Do you anticipate any technological hurdles from scaling up the process?
DS: Scale-up should not be a problem, as it is a moderate-temperature vat-based process. It has been consistent from beaker size to 250L. In fact, the bigger the vat, the better the settling effect. We are currently thinking about a 200,000t/yr plant at first but an ideal plant would probably be most effective at 600,000t/yr. Another option would be to have a modular approach with many vats.
GC: What concerns do cement producers have at present?
DS: In principle cement producers are keen to see this technology developed, as they have serious concerns about reduced FGD supplies. However, they have requirements regarding particle size, morphology, water content, etc, that need to be addressed. We aren’t yet at the scale that will allow us to give a cement plant enough gypsum to perform trials. We also need to be able to reliably supply gypsum. That’s why we need the pilot plant; to demonstrate that the gypsum works and that the process is reliable.
GC: Thank you for your time and all the best with the commercialisation of the process.
DS: Thank you very much indeed. Carbon Cycle is seeking investment partners to help us deliver our process to industry. We would be happy to talk to any companies or partners who want to work with us in this regard.