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New developments in alternative cement

16 October 2024

One unusual thing about coverage of cement in the media is the way that discussions often centre precisely on its absence – that is, on alternatives to cement. These alternatives boast unique chemistries and performance characteristics, but are all produced without Portland cement clinker. They are generally called ‘alternative cements,’ perhaps because ‘cement-free cement’ does not have such a commercially viable ring to it. This contradictory tendency reached a new high in the past week, with developments in alternative cement across Asia, Europe, the Middle East and North America. Together, they hint at a more diverse future for the ‘cement’ industry than the one we know today.

Asia

In Indonesia, Suvo Strategic Minerals has concluded tests with Makassar State University of a novel nickel-slag-based cement. Huadi Nickel-Alloy Indonesia supplied raw materials, and tests showed a seven-day compressive strength of 37.5MPa. Suvo Strategic Minerals says that a partnership with Huadi Nickel-Alloy Indonesia for commercial production is a likely next step.

Europe

Cement producer Mannok and minerals company Boliden partnered with the South Eastern Applied Materials (SEAM) research centre in Ireland to launch a project to develop supplementary cementitious materials (SCMs) from shale on 7 October 2024. The project will additionally investigate CO2-curing of cement paste backfill for use in mines. Irish state-owned global commerce agency Enterprise Ireland has contributed €700,000 in funding.

UK-based SCM developer Karbonite expects to launch trial production of its olivine-based SCM with a concrete company in 2025. The start-up launched Karbonite Group Holding BV, with offices in the Netherlands, to facilitate this new phase. Karbonite’s SCM is activated at 750 – 850°C and sequesters CO2 in the activation process, resulting in over 56% lower CO2 emissions than ordinary Portland cement (OPC). Managing director Rajeev Sood told Global Cement that talks are already underway for subsequent expansions into the UAE and India.

Back in the UK, contractor John Sisk & Son has received €597,000 from national innovation agency Innovate UK. John Sisk & Son is testing fellow Ireland-based company Ecocem’s <25% clinker cement technology in concrete for use in its on-going construction of the Wembley Park mixed development in London.

At the same time, Innovate UK granted a further €3.23m to other companies for concrete decarbonisation. Recipients included a calcined clay being developed by Cemcor, an SCM being developed from electric arc furnace byproducts by Cocoon, a geopolymer cement technology being developed by EFC Green Concrete Technology UK and an initiative to develop alternative cement from recycled concrete fines at the Materials Processing Institute in Middlesbrough. Also included was the Skanska Costain Strabag joint venture, which is working on the London stretch of the upcoming HS2 railway. The joint venture, along with partners including cement producer Tarmac and construction chemicals company Sika UK, will test low-kaolinite London clay as a raw material with which to produce calcined clay as a cement substitute in concrete structures in HS2’s rail tunnels.

Middle East

Talks are underway between UK-based calcined clay producer Next Generation SCM and City Cement subsidiary Nizak Mining Company over the possible launch of a joint venture in Riyadh, Saudi Arabia. The joint venture would build a 350,000t/yr reduced-CO2 concrete plant, which would use alternative cement based on Next Generation SCM’s calcined clay.

North America

Texas-based SCM developer Solidia Technologies recently patented its carbonatable calcium silicate-based alternative cement, which sequesters CO2 as it cures.

Meanwhile, C-Crete Technologies made its first commercial pour of its granite-based cement-free concrete in New York, US. C-Crete Technologies says that the product offers cost and performance parity with conventional cement, with net zero CO2 emissions. Its raw material is globally more abundant than the limestone used as a raw material for clinker. Other abundantly available feedstocks successfully deployed within C-Crete Technologies’ repertoire include basalt and zeolite.

Across New York State, in Binghamton, KLAW Industries has succeeded in replacing 20% of concrete’s cement content with its powdered glass-based SCM, Pantheon. KLAW Industries has delivered samples to local municipalities and the New York State Department of Transportation. Its success expands the discussion of possible circular cement ingredients from the industrial sphere into post-consumer resources.

In Calgary, Canada, a novel SCM has drawn attention from one of the major cement incumbents: Germany-based Heidelberg Materials. It invested in local construction and demolition materials (CDM)-based SCM developer EnviCore on 9 October 2024. The companies plan to build a pilot plant at an existing Heidelberg Materials CDM recycling centre.

Conclusion

Alternative cement developers are still finding the words to talk about their products. They may be more than ‘supplementary’ up to the point of entirely supplanting 100% of clinker. Product webpages offer ‘hydraulic binder,’ ‘pozzolan’ and even ‘cement.’ As alternative ‘cements’ are developed, they build on the work of pioneers like Joseph Aspdin and Louis Vicat. Start-ups and their backers are now reaching commercial offerings, on a similar-but-different footing to cement itself. None of these novel materials positions itself as the sole, last-minute ‘super sub’ in the construction sector’s confrontation with climate change. Rather, they are a package of solutions which can combine into a net zero-emissions heavy building materials offering, hopefully before 2050.

Related to this is the need for ‘technology neutral’ standards, as championed this week by the Alliance for Low-Carbon Cement and Concrete (ALCCC), along with 23 other European industry associations, civil society organisations and think tanks. The term may sound new, but the concept is critical to the eventual uptake of alternative cements: standards, the ALCCC says, should be purely performance-based. They ought not attempt to define what technology, for example cement clinker, makes a suitable building material. According to the ALCCC, Europe’s building materials standards are not technology neutral, but instead ‘gatekeep’ market access, to the benefit of conventional cement and the exclusion of ‘proven and scalable low-carbon products.’

At the same time, cement itself is changing. Market research from USD Analytics showed an anticipated 5% composite annual growth rate in blended cement sales between 2024 and 2032, more than doubling throughout the period from US$253bn to US$369bn. If you can’t beat it, blend with it!

 

For a further discussion of alternative cement and binders in Europe, see Global Cement’s interview with ALCCC co-ordinator Joren Verschaeve in the forthcoming November issue of Global Cement Magazine on 17 October 2024.

Published in Analysis
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Global Cement and Concrete Association announces Innovandi Open Challenge 2023 shortlist

30 June 2023

World: The Global Cement and Concrete Association (GCCA) has named the 15 anticipated deliverers of low-CO2 cement and concrete production shortlisted for participation in its second Innovandi Open Challenge. The association chose the start-ups based on their potential to deliver CO2 emissions reduction in the global cement and concrete sector in line with its Concrete Future 2050 Net Zero Roadmap. The applicants are presenting their pitches to GCCA members on 30 June 2023. All those accepted will gain access to members' plants, labs, networks and expertise. The following start-ups made the Innovandi Open Challenge 2023 shortlist:

Arrakis Materials

US

Carbon negative materials for concrete

Chement

US

Room temperature cement production

EcoAdmix Global

UK

Nanotechnology ('HDT') for concrete

EcoLocked

Germany

Biocarbon-based admixtures

EnviCore

Canada

Low temperature supplementary cementitious material production

Enzymatic

US

Carbon negative enzymatic concrete corrosion inhibition and recycling

Louis Structures

US

Municipal solid waste-based lightweight aggregates

MEP - SeaMix

US

Basalt fibre and graphene-based admixture

Nano Crete

US

Graphene-enhanced CO2 sequestration

Nanospan India

India

Graphene-based admixture

NeoCrete

New Zealand

Nano-activator for natural pozzolans

Queens Carbon

US

~500°C cementitious materials production

The Cool Corporation

UK

Carbon negative carbon nanotube-based additive for concrete

Ultra High Materials

US

Clinkerless cement

Versarien Graphene

UK

Graphene-based admixture ('Cementene')

GCCA cement director and innovation lead Claude Loréa said “We received more than 70 quality applications, so drawing up a shortlist was challenging." Loréa continued "Our essential industry needs something easily scalable and affordable. Those start-ups on the list demonstrated the most potential, and we look forward to hearing more about their ideas. But we’ll also be keeping in touch with other start-ups who didn’t make this year’s shortlist, with future projects in mind.”

Published in Global Cement News
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Hanson supplies crushed basalt for first CO2 sequestration field trial in the UK

28 May 2021

UK: Hanson, part of Germany-based HeidelbergCement, has supplied basalt from its Builth Wells, Powys quarry to the world’s first CO2 sequestration field trial in the Brecon Beacons. The trial uses local live soil enriched with basalt for enhanced CO2 sequestration in a reforested 11ha woodland. Enhanced rock weathering takes crushed basalt, a by-product of quarrying, and applies it to the soil to capture CO2 and provide essential nutrients to fertilise trees and the fungi in the soil that support tree growth. The building materials producer says it is a method that has been proven to be successful in sugar beet and pea crops.

Sustainability director Marian Garfield said, “Hanson is focussed on climate protection and carbon reduction, and enhancing biodiversity net gain are two of our key 2030 commitments.” She added, “We are excited to be involved with this project, which aims to determine whether basalt can accelerate the removal of CO2 from the atmosphere in the creation of new woodland and could therefore potentially play a vital role in helping tackle the climate crisis.”

Published in Global Cement News
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